A new coupling reaction for the synthesis of ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl ligands.
نویسندگان
چکیده
The reaction of RuCl(3)(solv.)(n) with tert-butylacetylene in methanol or ethanol leads to the formation of chloro-bridged half-sandwich complexes with sterically demanding cyclopentadienyl ligands, which are of high interest as starting materials for the synthesis of novel Ru catalysts.
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عنوان ژورنال:
- Chemical communications
دوره 18 شماره
صفحات -
تاریخ انتشار 2007